The Briton, having qualified in 11th for the first sprint race of the season, which will take place on Saturday afternoon, remained at the top of the leaderboard with his 1m19.457s.
That gave him a slender 0.08s cushion to Perez, while Ferrari’s Leclerc was 0.2s in arrears.
Perez comfortably led the way in the first half of the hour-long session, as he kept whittling away at his personal best lap on the red-walled soft tyres to maintain his place atop the times.
It was Lance Stroll who first emerged onto the fully dry track, opting for a set of mediums as he was swiftly joined by Haas’ Mick Schumacher and the Alfa Romeo of Zhou Guanyu.
Lando Norris set an early banker to take top spot with a 1m23.821s before Lewis Hamilton brought the benchmark down to 1m21.880s on a set of mediums after eight minutes.
But then it was Perez who moved and, for a large chunk of the early afternoon run, remained at the head of the leaderboard as he completed a stint on the C4 compound soft Pirellis.
The Red Bull driver guided his RB18 around the three-mile lap in 1m19.978s to find eight tenths over his team-mate initially, while Yuki Tsunoda led the medium runners in third.
Sergio Perez, Red Bull Racing RB18
Photo by: Mark Sutton / Motorsport Images
Perez appeared to be on a one-third-capacity low-fuel dash to mimic the shorter afternoon sprint race as he consistently turned in a run of laps in the high 1m19s and low 1m20s.
By comparison, Max Verstappen was in the high 1m20s for the bulk of his soft tyre run and occasionally nudged the 1m21s to suggest a simulation more akin to the full grand prix.
During his quick stint, Perez again improved to a 1m19.790s to lead over Russell.
But the Mercedes returned to the track after half an hour for a one-lap show run on soft tyres, with the Brit posting a 1m19.457s to top the session aboard his W13 by 0.3s over Perez.
Meanwhile, Hamilton dipped under the 1m20s for an eventual fourth to pull four tenths on defending champion…
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